Facile and Sensitive Spectrophotometric Method for the Determination of Vanadium
 
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Department of Post Graduate Studies and Research in Chemistry Mangalore University, Mangalagangothri – 574 199, Karnataka, India
CORRESPONDING AUTHOR
Badiadka Narayana   

Department of Post Graduate Studies and Research in Chemistry Mangalore University, Mangalagangothri – 574 199, Karnataka, India
Publish date: 2017-10-06
 
Eurasian J Anal Chem 2009;4(2):141–151
KEYWORDS
ABSTRACT
Highly sensitive and simple spectrophotometric method is described for the determination of vanadium(V) using a new reagent azure B. The method is based on the reaction of vanadium(V) with potassium iodide in an acidic condition to liberate iodine, the liberated iodine bleaches the blue color of azure B and is measured at 636 nm. The decrease in absorbance is directly proportional to vanadium concentration. The method obeys Beer’s law over a concentration range of 0.02–9.0 μgmL-1 vanadium. The molar absorptivity, sandell’s sensitivity, detection limit and quantification limit of the reaction system were found to be 4.33 × 104 L mol−1 cm-1, 0.0011 µg cm−2, 0.75 µg ml−1 and 2.27 µg ml−1 respectively. The optimum reaction conditions and other analytical parameters have been evaluated. The proposed procedure has been successfully applied to the determination of vanadium in water, soil, plant material, urine, pharmaceutical preparations and steel samples. The results were compared to those obtained with the reference method.
 
REFERENCES (37)
1.
Pyrzynska K (2005) recent developments in spectrophotometric methods for determination of vanadium. Mikrochim Acta 149: 159.
 
2.
Taylor M J C, Staden J F V (1994) Spectrophotometric determination of vanadium(IV) and vanadium(V) in each other's presence. Review. Analyst 119: 1263.
 
3.
Valero J (1991) Determinacion Fotometrica de Vanadio Mediante Sistemas Ternarios. Bol Soc Quim Peru 57: 23.
 
4.
Welz B, Sperling M (1999) Atomic Absorption Spectrometry, 3rd edition, Wiley VCH; Weinheim.
 
5.
Sabbioni E, Kueera J, Pietra R, Vesterberg O (1996) A critical review on normal concentrations of vanadium in human blood, serum, and urine Sci. Total Environ.188 : 49.
 
6.
Barceloux D G (1999) Vanadium. Clin. Toxicol. 37: 265.
 
7.
Tsiani E, Fantus I G (1997) Vanadium compounds: biological actions and potential as pharmacological agents. Trends Endocrinol. Metab. 8: 51.
 
8.
Badmaev M D V, Prakash S, Majeed M (1999) Vanadium: A review of its potential role in the fight against diabetes. J Altern Compl Med 5: 273.
 
9.
Poucheret P, Verma S, Grynpas M D, McNeill J H (1998) Vanadium and diabetes. Mol Cell Biochem. 188: 73.
 
10.
De Beer H, Coetzee P P (1994) Vanadium speciation by ion chromatography. Fresenius J Anal Chem 348: 806.
 
11.
Wang H, Zang H. S, Cheng J K (1995) Determination of V(V), Nb(V) and Ta(V) as their 2-(5-nitro-2-pyridylazo)-5- diethylaminophenol complexes by reversed-phase high performance liquid chromatography. Fresenius J Anal Chem 351: 683.
 
12.
Miura J H (1990) Determination of trace amounts of vanadium in natural waters and coal fly ash with 2-(8-quinolylazo)-5-(dimethylamino)phenol by reversed-phase liquid chromatography-spectrophotometry. Anal Chim 62: 1424.
 
13.
Ensafia A, Naderi B (1997) Catalytic determination of ultra trace amounts of vanadium with detection by linear sweep voltammetry. Fresenius J Anal Chem 358: 480.
 
14.
Serrat F B, Morell G B (1994) Colorimetric method for the determination of vanadium with tannic acid in water and oils. Fresenius J Anal Chim 349: 717.
 
15.
Chakraborty R, Das K (1994) Determination of of vanadium by ETAAS using chromium nitrate as chemical modifier. Fresenius J Anal Chem 349: 774.
 
16.
Yaman M, Gucer S (1994) Determination of vanadium in biological matrices by flame atomic absorption spectrometry with activated carbon enrichment. Fresenius J Anal Chem 350: 504.
 
17.
Kawakubo S, Ogihara K, Iwatsuki M (1995) Catalytic spectrofluorimetric determination of vanadium using oxidation of o-phenylenediamine with bromate in the presence of gallic acid. Analyst 120: 2719.
 
18.
Dupont V, Auger Y, Jeandel C, Warter M (1991) Determination of vanadium in seawater by inductively coupled plasma atomic emission spectrometry using chelating resin column preconcentration. Anal Chem 63: 520.
 
19.
Coetzee P P Fischer J L, Mingsong H (2002) The separation and simultaneous determination of V(IV) and V(V) species complexed with EDTA by IC-ICP-OES. Water SA 28: 37.
 
20.
Danzaki Y (1992) Determination of sub-μg/g amounts of vanadium in iron by Nbenzoyl-N-phenylhydroxylamine-chloroform solvent extraction/ICP-AES. Fresenius J Anal Chem 342: 103.
 
21.
Qiufen H, Yang G, Yin J (2004) Study on solid phase extraction and spectrophotometric determination of vanadium with 2-(2-quinolylazo)-5- diethylaminophenol. Bull Korean Chem Soc 25: 263.
 
22.
Kiran Kumar T N, Revanasiddappa H D (2005) Spectrophotometric Determination of vanadium using variamine blue and its application to synthetic, environmental and biological samples. Iranian J Chem Soc 2: 161.
 
23.
Sendra J M B, Valencia M C, Boudra S (1998) Speciation of vanadium (IV) and vanadium (V) with Eriochrome Cyanine R in natural waters by solid phase spectrophotometry. Fresenius J Anal Chem 360: 31.
 
24.
Chauhan R S, Kakkar L R (1992) Extractive separation and photometric determination of vanadium with benzoylacetone. Bull Chem Soc Jpn 65: 1033.
 
25.
Iranpoor N, Maleki N, Razi S, Safavi A (1992) Spectrophotometric determination of vanadium in different oxidation states with pyrogallol. Talanta 39: 281.
 
26.
Murthy G V R, Reddy T S, Rao S B (1989) Extraction and simultaneous spectrophotometric determination of vanadium(IV) and vanadium(V) in admixture with 2-hydroxyacetophenone oxime. Analyst 114: 493.
 
27.
Taylor M J C, Marshall G D, Williams S J S, Vanstaden J F, Sailing C (1996). The determination of vanadium(V) in the presence of vanadium(IV) using 4-(2- pyridylazo)resorcinol in a flow-injection manifold. Anal Chim Acta 329: 275.
 
28.
Kiril B G, Vanya D L, Atanas N D, Georgi I P (2007) The solvent extraction and spectrophotometric determination of vanadium (V) with 4-(2-thiazolylazo)resorcinol and tetrazolium salts. Cent Eur J Chem 5: 257.
 
29.
Zucchi C, Forneris M, Martinez L, Oisina R, Marchevsky E (1998) Sensitive spectrophotometric determination of vanadium with hydrogen peroxide and 2-(5- chloro-2-pyridylazo)-5-dimethylaminophenol after extraction with N-benzoyl-Nphenylhydroxylamine. Fresenius J Anal Chem 360: 128.
 
30.
Shigenori N, Tanaka E, Mizutani Y (2003) Flow-injection spectrophotometry of vanadium by catalysis of the bromate oxidation of N,N′-bis(2-hydroxyl-3- sulfopropyl)-tolidine. Talanta 61: 203.
 
31.
Marczenko Z (1986) Separation and Spectrophotometric Determination of Elecments, 2nd edition, Ellis Harwood Ltd., Chickester, England.
 
32.
Glick D (1973) Methods of Biochemical Analysis, JohnWiley.USA.
 
33.
Ahmed M J, Banoo S (1999) Spectrophotometric method for determination of vanadium and its application to industrial, environmental, biological and soil samples. Talanta 48: 1085.
 
34.
Suresh Kumar K, Kang S H, Suvardhan K, Kiran K (2007) Facile and sensitive spectrophotometric determination of vanadium in various samples. Environ Toxicol Phar 24: 37.
 
35.
Narayana S L, Reddy K J, Reddy S A N, Sarala Y, Reddy A V (2008) A highly sensitive spectrophotometric determination of micro amounts of vanadium(V) in environmental and alloy samples by using 3,4-dihydroxybenzaldehydeisonicotinoylhydrazone (3,4-DHBINH). Environ Monit Assess. 144: 341.
 
36.
Zhou N, He C X, Gu N L, Chen P B (1994) Selective method for the spectrophotometric determination of vanadium in the presence of other refractory elements with 2,2 -iminodibenzoic acid. Analyst 119: 2105.
 
37.
Marczenko Z, Lobinski R (1988) Flotation-Spectrophotometric Determination of Vanadium with 3,5-Dinitrocatechol and Rhodamine B. Anal Sci 4: 629.
 
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