Sodium Lignosulfonate as a Friendly-Environment Corrosion Inhibitor for Zinc Metal in Acidic Media
 
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1
Department of Chemistry, college of arts and sciences, University of Petra, P.O. Box: 961343, Amman 11196, Jordan
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Department of Chemistry, The University of Jordan, Amman 11942, Jordan
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Chemistry Department, Basra University, Basra, Iraq
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Department of Chemistry, American University of Madaba, Madaba, Jordan
Publication date: 2017-10-05
 
Eurasian J Anal Chem 2015;10(1):10–18
 
KEYWORDS
ABSTRACT
The corrosion inhibition property of sodium lignosulfonate is investigated by three different independent monitoring techniques. These methods include weight loss measurements, electrical conductance and potentiodynamic polarization. Solutions with and without sodium lignosulfonate in 0.01 M HCl and 0.1 M HCl were prepared at 20oC to study the influence of sodium lignosulfonate on the corrosion of zinc sheets. The results obtained from the three different methods indicate the protection role of sodium lignosulfonate, which is considered as a friendly-environment corrosion inhibitor, in the corrosion of zinc sheets. The reduction of the zinc corrosion in solutions with HCl and different concentrations of sodium lignosulfonate using potentiodynamic polarization followed the order: 30 mM > 10 mM > 5 mM >1 mM. The obtained results from weight loss, potentiodynamic polarization and electrical conductance experiments were in good agreement with each other.
 
REFERENCES (20)
1.
Baboian R (2005) Corrosion Tests and Standards Application and Interpretation,ASTM international, West Conshohocken, p 152.
 
2.
Thomas JGN (1976) Mechanism of Corrosion Prevention by Inhibitors. In: Shrier L Corrosion, Vol. 2, Newness-Butterworth, London, p 36.
 
3.
Sastri VS (2011) Corrosion Inhibitors: Principles and Applications, John Wiley and sons, United Kingdom, p 34.
 
4.
Department of Energy (1993) Corrosion, Springfield, Washington, p 45.
 
5.
Argyopoulos DS, and Manachem SB (1998) lignin. In: Kaplan DL, Biopolymers from Renewable Resources, Springer, Berlin, p 292.
 
6.
Bryce JRG (1980) Alkaline Pulping. In: Casey JP, Pulp and Paper Chemistry and Chemical Technology, Third Edition, Vol. 1, p 377.
 
7.
Gardon JL, and Mason SG (1955) Physicochemical studies of lignosulfonates: preparation and properties of fractionated samples. Canadian Journal of Chemistry 33: 1477.
 
8.
Rana D, Neale GH, and Hornof V (2002) Surface tension of mixed surfactant systems: lignosulfonate and sodium dodecyl sulfate, Colloid polym Sci 280: 777.
 
9.
Ouyang X, Qiu X, Lou H, and Yang D (2006) Corrosion and Scale Inhibition Properties of Sodium Lignosulfonate and Its Potential Application in Recirculating Cooling Water System. Ind Eng Chem Res 45: 5716.
 
10.
Properties of Sodium Lignosulfonate and Its Potential Application in Recirculating Cooling Water System. Ind Eng Chem Res 45: 5716.
 
11.
Lou H, Qiu X, Ouyang X , and Chen H (2011) Study of the dispersion, scale inhibition and corrosion inhibition of sodium lignosulfonate from masson pine. Jingxi Huagong/Fine Chemicals 18: 588.
 
12.
Altwaiq A, Khouri SJ, Al-luaibi S, Lehmann R, Drücker H, and Vogt C (2011) The inhibition behavior of alkali lignin in the corrosion of different alloys, Journal of Materials and Environmental Science 2: 259.
 
13.
National Association of Corrosion Engineers (NACE) (2005) Standard RP0775-2005,Preparation, Installation, Analysis, and Interpretation of Corrosion Coupons in Oilfield Operations, NACE, Houston, p 1.
 
14.
Ghasemi Z, and Tizpar A (2007) Studies on Corrosion Resistance and Electrochemical Behavior of Pb-Sb-As-S Alloys as Positive Grids in Lead-acid Batteries. Int J Electrochem Sci 2: 700.
 
15.
Laidler KJ, Moiser JH, and Sanctuary BC (2003) Physical chemistry, Houghton Mifflin, Boston, p 291.
 
16.
Akbarzadeh E (2014) Corrosion inhibition of thermal hydrolyzed lignin on mild steel in hydrochloric acid. The journal of corrosion science and engineering: 16.
 
17.
Dence CW, and Lin SY (1992) General Structural Features of Lignin, Springer, Berlin, p 31.
 
18.
Maayta A.K, and Al-Rawashdeh NA (2004) Inhibition of acidic corrosion of pure aluminum by some organic compounds. Corrosion science, 46: 1129.
 
19.
Deng Y, Wu Y, Qian Y, Ouyang X, Yang D, and Qiu X (2010) Adsorption and desorption behaviors of lignosulfonate during the self-assembly of multilayers, BioResources, 5: 1178.
 
20.
Kissinger PT, and Heineman WR (1983) Cyclic Voltammetry, Journal of Chemical Education, 60: 702.
 
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