RESEARCH PAPER
Synthesis a New Schiff Base as a Chelating Agent for Reliable Quantification of Zinc from Water and Biological Samples
 
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1
Department of Chemistry, Faculty of Science, University of Birjand, Birjand, IRAN
2
Sharif University of Technology, Tehran, IRAN
Publish date: 2018-10-02
 
Eurasian J Anal Chem 2018;13(5):em65
KEYWORDS
ABSTRACT
A new Schiff base, 2-[(4-Chloro-2-oxo-2H-chromen-3-ylmethylene)-amino]-propionic acid was successfully synthesized and characterized by proton nuclear magnetic resonance (1H NMR), carbon-13 nuclear magnetic resonance (13C NMR), Fourier transform infrared (FT-IR), elemental analysis (CHN) and UV–Vis spectroscopy. It was found out that the synthesized Schiff base could be used as a novel and reliable candidate to detect and quantify of Zn (II) ions in water and biological samples. Some effective parameters on quantification of Zn (II), such as pH, Schiff base and salt concentration were inspected by a (23) full factorial design using Design-Expert, software. Under optimum conditions, the calibration graph was linear in the range 0.04–10.0 μg mL−1 with a limit of detection of 0.01 μg mL−1. The proposed method was successfully applied to the rapid determination of Zn (II) in water and biological samples. The validation was performed by inductively coupled plasma atomic emission spectrometry (ICP-AES) with satisfactory results.
 
REFERENCES (38)
1.
Terres-Martos C, Navarro-Alarcón M, Martín-Lagos F, Giménez Martínez R, De La Serrana HLG, López-Martı́nez MC. Water Res. 2002;36:1912. https://doi.org/10.1016/S0043-....
 
2.
Yılmaz S, Tokalıoglu S, Sahan S, Ulgen A, Sahan A, Soykan C. J. Trace Elem. Med. Biol. 2013;27:85. https://doi.org/10.1016/j.jtem....
 
3.
Trivedi P, Axe L. Environ. Sci. Technol. 2000;34:2215. https://doi.org/10.1021/es9911....
 
4.
Tupe RS, Tupe SG, Tarwadi KV, Agte VV. Metab. Clin. Exp. 2010;59:1603. https://doi.org/10.1016/j.
 
5.
metabol.2010.02.020.
 
6.
Yanagisawa H, Miyakoshi Y, Kobayashi K, Sakae K, Kawasaki I, Suzuki Y, Tamura J. Toxicol. Lett. 2009;19:15. https://doi.org/10.1016/j.toxl....
 
7.
Calder PC, Yaqoob P. in Diet, Immunity and Inflammation. (Eds: K. Gruber, L. Rink) 2013:123-1567 (Woodhead Publishing: Cambridge).
 
8.
Haase H, Overbeck S, Rink L. Perspect. Exp. Gerontol. 2008;43:394. https://doi.org/10.1016/.
 
9.
j.exger.2007.12.002.
 
10.
Salgueiro MJ, Zubillaga MB, Lysionek AE, Caro RA, Weill R, Boccio JR. Nutrition 2002;18:510. https://doi.org/10.1016/S0899-....
 
11.
Alam IA, Sadiq M. Environ. Pollut. 1989;57:167. https://doi.org/10.1016/0269-7....
 
12.
Almeida MIGS, Chan C, Pettigrove VJ, Cattrall RW, Kolev SD. Environ. Pollut. 2014;193:233. https://doi.org/10.1016/j.envp....
 
13.
Patterson KY, Pehrsson PR, Perry CR. J. Food Compos. Anal. 2013;31:46. https://doi.org/10.1016/j.jfca.
 
14.
03.004.
 
15.
Ghasemi JB, Hashemi B. Environ. Monit. Assess. 2011;183:57. https://doi.org/10.1007/s10661....
 
16.
Abdolmohammad-Zadeh H, Sadeghi GH. Anal. Chim. Acta. 2009;649:211. https://doi.org/10.1016/j.aca.....
 
17.
Carletto JS, Roux KCDP, Maltez HF, Martendal E, Carasek E. J. Hazard. Mater. 2008;157:88. https://doi.org/10.1016/j.jhaz....
 
18.
Zhu X, Liang H, Zhao S, Yan H, Han D. Int. J. Environ. Anal. Chem. 2008;88:689. https://doi.org/10.1080/030673....
 
19.
Kiptoo JK, Ngila JC, Silavwe ND. Microchim. Acta. 2008;160:211. https://doi.org/10.1007/s00604....
 
20.
Chang X, Luo H, Cui Y, Zhu X, Zheng HuY, He Q. J. Mol. Struct. Res. 2008;891:45. https://doi.org/10.1016/j.mols....
 
21.
Suvardhan K, Suresh Kumar K, Rekha D, Kiran K, Jaya Raj B, Chiranjeevi P. J. Anal. Chem. 2007;62:336. https://doi.org/10.1134/S10619....
 
22.
Khajeh M. J. Hazard. Mater. 2009;172:385. https://doi.org/10.1016/j.jhaz....
 
23.
Tormen L, Gil RA, Frescura VLA, Martinez LD, Curtius AJ. Spectrochim. Acta B 2010;65:959. https://doi.org/10.1016/j.sab.....
 
24.
Bersier PM, Howell J, Bruntlett C. Analyst, 1994;119:219. https://doi.org/10.1039/AN9941....
 
25.
Pesavento M, Alberti G, Biesuz R. Anal. Chim. Acta. 2009;631:129. https://doi.org/10.1016/.
 
26.
j.aca.2008.10.046.
 
27.
Welz B, Sperling M. Atomic absorption spectrometry 1999 (Wiley-VCH: Weinheim).
 
28.
Veith M, Mathur S, Mathur C. Polyhedron 1998;17:1005. https://doi.org/10.1002/chin.1....
 
29.
Witkop WB, Ramachandran LK. Metabolism 1964;13:1016. https://doi.org/10.1016/S0026-....
 
30.
Gerdemann C, Eicken C, Krebs B. Acc. Chem. Res. 2002;35:183. https://doi.org/10.1021/ar9900....
 
31.
Kabeer AS, Baseer M, Mote N. Asian J. Chem. 2001;13:496.
 
32.
Wang X, Wu G, Wang F, Wei W, Sun Y. Chin J. Catal. 2011;32:1812. https://doi.org/10.1016/S1872-....
 
33.
Bellamy LJ. The infra- red spectra of complex molecules 1975 (Wiley; New York).
 
34.
Khani R, Sobhani S, Hossein Beyki M. J. Colloid. Interface. Sci. 2016;466:198. https://doi.org/10.1016/j.jcis....
 
35.
Myers RH, Montgomery DC. Response Surface Methodology 2001 (Wiley: New York).
 
36.
Moorty S, Sundaram V, Rao NS. Indian J. Chem. 1973;11:854. https://doi.org/10.1002/chin.1....
 
37.
Singh HL, Singh J. Res. Chem. Intermed. 2013;39:1997. https://doi.org/10.1007/s11164....
 
38.
Harrington JM, Young DJ, Essader AS, Sumner SJ, Levine KE. Biol. Trace Elem. Res. 2014;160:132. https://doi.org/10.1007/s12011....
 
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