Electrochemical Synthesis of Coordination Compounds of Antimony(III) Thiolates
DOI:
https://doi.org/10.53555/k2bddx45Keywords:
Antimony, Thiols, Tetrabutylammonium chlorideAbstract
The antimony(III) thiolate, synthesized, have been refluxed with 1,10 - phenanthroline and 2,2’ - bipyridyl separately in various solvents like methanol, ethanol, benzene and acetonitrile for 48 hours in order to prepare their coordination compounds. Analytical data and infrared spectral data of the products so obtained show that the ligand molecules could not enter the coordination sphere of these antimony(III) thiolate. It is, therefore, considered worthwhile that the ligand may be added to these alkoxides before these form alkoxy bridges and get polymerized. Therefore, in addition to thiol and supporting electrolyte, 1.0 g of the ligand (1,10 - phenanthroline or 2,2’ - bipyridyl) was also added to these systems and the solution was electrolyzed at antimony anode and inert platinum cathode for ten hours. The products obtained are insoluble in commonly used organic solvents and do not melt upto 3000C. Elemental analysis and infrared data conform to general formula, Sb(SR)3.L.
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